Equivalence Point pH Formula:
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The equivalence point pH formula calculates the pH at the equivalence point of a weak acid-strong base titration. It accounts for the hydrolysis of the conjugate base formed during the titration.
The calculator uses the equivalence point pH formula:
Where:
Explanation: The formula combines the effects of the weak acid's pKa and the concentration of the resulting conjugate base solution.
Details: Knowing the equivalence point pH is crucial for selecting appropriate indicators in acid-base titrations and understanding the titration curve's shape.
Tips: Enter the weak acid's pKa and its initial concentration in molarity (M). Both values must be positive numbers.
Q1: Does this formula work for strong acid-strong base titrations?
A: No, for strong acid-strong base titrations, the equivalence point pH is always 7 at 25°C.
Q2: What if I have a weak base-strong acid titration?
A: For weak base-strong acid titrations, a different formula is used that involves pKb instead of pKa.
Q3: How does temperature affect the equivalence point pH?
A: Temperature affects the pKa of the weak acid and the autoionization of water (Kw), which would slightly alter the calculated pH.
Q4: Why is the equivalence point pH basic for weak acid-strong base titrations?
A: Because the conjugate base of the weak acid hydrolyzes in water, producing hydroxide ions and making the solution basic.
Q5: What's the range of valid pKa values for this calculation?
A: Typically pKa values between 2-12 give meaningful results, as very strong or very weak acids may require different treatment.